Integrated Nanostructured Systems

A UB 2020 Academic and Strategic Strength


Department of ChemistryAssistant Professor
University at Buffalo
411 Natural Sciences Complex
Buffalo, NY 14260

PH: (716) 645-6800, ext. 2124
Web: http://www.chem.buffalo.edu/banerjee.php
E: sb244@buffalo.edu

Laboratory
University at Buffalo
407 Natural Sciences Complex
Buffalo, NY 14260

PH: (716) 645-6800, ext. 2125

Research


Research Images

Vanadium oxide nanowires

Vanadium oxide nanowires assembled in a field-effect transistor geometry by AC dielectrophoresis.

Research Interests

Synthesis and surface chemistry of oxide nanoparticles; directed assembly and device integration of nanoparticles, nanowires, and carbon nanotubes; functional nanocrystal films for gate dielectric and photovoltaics; raman spectroscopy and XANES characterization of nanomaterials.

Summary of Research

Since starting at UB in the fall of 2007, our research interests are focused on:

  • The synthesis of HfxZr1-xO2 nanoparticles and their assembly into ordered thin films and superlattices for capacitor applications.
  • The controlled synthesis of VOx nanowires and their integration into transistor geometries.
  • The chemical functionalization of graphene with semiconductor nanoparticles for optoelectronics applications.
  • The synthesis of CeO2-Au composite nanoparticles from organometallic precursors for catalytic applications.

We are especially interested in understanding the role of finite size effects in influencing the individual and ensemble electronic properties of nanomaterials. Towards this end, we use a variety of techniques for detailed structural characterization, focusing primarily on Raman spectroscopy and X-ray absorption spectroscopy approaches.

Specialized Instrumentation

Raman microprobe system with multiple laser excitations; Malvern zetasizer for particle size analysis and zeta potential measurements.

Publications

S. Banerjee, B. E. White, L. Huang, S. O'Brien, and I. P. Herman. "Positioning of Nanotubes by AC Dielectrophoresis Using Floating Posts." Appl. Phys. A 2007, 86, 415.

D. Lee, S. Jia, S. Banerjee, J. Bevk, I. P. Herman, and J. W. Kysar. "Viscoplastic and Granular Behavior in Films of Colloidal Nanocrystals." Phys. Rev. Lett. 2007, 98, 026103/1.

S. Banerjee, D.-I. Kim, Y. Mao, R. D. Robinson, S. S. Wong, and I. P. Herman. "Observation of First-Order Fano Asymmetry in Raman Spectra of SrTiO3 and CaxSr1-xTiO3 Perovskite Nanocubes." Appl. Phys. Lett. 2006, 89, 223130/1.

S. Banerjee, B. E. White, L. Huang, S. O'Brien, and I. P. Herman. "Precise Positioning of Carbon Nanotubes by AC Dielectrophoresis." J. Vac. Sci. Technol. B 2006, 24, 3173.

S. Banerjee, S. Jia, D.-I. Kim, R. D. Robinson, J. Bevk, and I. P. Herman. "Analysis of Strain Relaxation in CdSe Nanocrystal Films by Raman Microprobe Analysis." Nano Lett. 2006, 6, 175.

T. Hemraj-Benny, S. Banerjee, S. Sambasivan, M. Balasubramanian, D. A. Fischer, J. A. Misewich, and S. S. Wong. "Near-edge X-ray Absorption Fine Structure Spectroscopy as a Tool for Investigating Nanomaterials." Small 2006, 2, 26.

S. Banerjee, T. Hemraj-Benny, S. Sambasivan, D. A. Fischer, J. A. Misewich, and S. S. Wong. "NEXAFS Investigations of Order in Carbon Nanotube-Based Systems." J. Phys. Chem. B 2005, 109, 8489.

S. Banerjee, T. Hemraj-Benny, and S. S. Wong. "Covalent Surface Chemistry of Single-Walled Carbon Nanotubes." Adv. Mater. 2005, 17, 17.

S. Banerjee, T. Hemraj-Benny, and S. S. Wong. "Routes Towards Separating Metallic and Semiconducting Nanotubes." J. Nanosci. Nanotech. 2005, 5, 841.

S. Banerjee and S. S. Wong. "Demonstration of Diameter-Selective Reactivity in the Sidewall Ozonation of SWNTs by Resonance Raman Spectroscopy." Nano Lett. 2004, 4, 1445.

S. Banerjee and S. S. Wong. "Formation of CdSe Nanocrystals on Oxidized, Ozonized Single-Walled Carbon Nanotube Surfaces." Chem. Commun. 2004, 1866.

S. Banerjee, T. Hemraj-Benny, M. Balasubramanian, J. A. Misewich, D. A. Fischer, and S. S. Wong. "Structural and Spectroscopic Study of Purified, Ozonized Multi-Walled Carbon Nanotubes." ChemPhysChem 2004, 5, 1416.

T. Hemraj-Benny, S. Banerjee, and S. S. Wong. "Interactions of Single-Walled Carbon Nanotubes with Lanthanide Salts." Chem. Mater. 2004, 16, 1855.

S. Banerjee, T. Hemraj-Benny, M. Balasubramanian, D. A. Fischer, J. A. Misewich, and S. S. Wong. "Ozonized Single-Walled Carbon Nanotubes Investigated using NEXAFS Spectroscopy." Chem. Commun. 2004, 772.

S. Banerjee and S. S. Wong. "Selective Metallic Tube Reactivity in the Solution-Phase Osmylation of Single-walled Carbon Nanotubes." J. Am. Chem. Soc. 2004, 126, 2073.

S. Banerjee and S. S. Wong. "In Situ Growth of 'Fused-, Ozonized Single-Walled Carbon Nanotubes - CdTe Quantum Dot Junctions." Adv. Mater. 2004, 16, 34. (Inside Cover)

Y. Mao, S. Banerjee, and S. S. Wong. "Large Scale Synthesis of Perovskite Nanostructures." J. Am. Chem. Soc. 2003, 125, 15718.

S. Banerjee and S. S. Wong. "In Situ Quantum Dot Growth on Multiwalled Carbon Nanotubes." J. Am. Chem. Soc. 2003, 125, 10342.

S. Banerjee, M. G. C. Kahn, and S. S. Wong. "Rational Chemical Strategies for Carbon Nanotube Functionalization." Chem. Eur. J. 2003, 9, 1898.